Compared with traditional liquid lithium batteries, solid-state lithium batteries (SSLB) use solid electrolytes instead of organic electrolytes. Their safety and energy density are greatly improved, which can effectively reduce safety hazards of electric vehicles and relieve users' range anxiety. Solid electrolyte, as an electronic insulator and ionic conductor, is one of the core elements of SSLB. At the same time, it has problems such as low ionic conductivity, large interface impedance, and poor interface st